Effect of Inhibitor Extract of Guava Leaf (Psidium guajava) on Corrosion Rate of Ammunition Case Caliber 7.62 mm in CH3COOH and HCl Media
DOI:
https://doi.org/10.54706/senastindo.v3.2021.151Keywords:
Ammunition, Brass, Corrosion, Inhibitor, Corrosion RateAbstract
Corrosion can occur in any metal, including brass metal as raw material for making ammunition casing. One way to inhibit corrosion is to use corrosion inhibitors which can be made using organic materials. Guava leaf (Psidium guajava) contain tannin compounds as corrosion inhibitors. In this study, the brass used was the casing of the MU-2TJ ammunition caliber 7.62 mm produced by PT. Pindad in 1992 and 1994. Corrosion rate was calculated by the method weight loss. Inhibitor preparation of guava leaf extract was carried out by maceration method, where 10 grams of dried guava leaf were dissolved in 100 mL water-ethanol solvent with various volume ratios of water : ethanol 7:3, 6:4, and 5:5, respectively. Brass with inhibitor and without inhibitor was immersed for 15 days or 360 hours in HCl and CH3COOH solution media. . The results showed that in CH3COOH media, the largest inhibitor efficiency was 42.12% by using guava leaf extract inhibitor with a ratio of volume water : ethanol 6:4 in CH3COOH 0.1 M solution, where the corrosion rate of brass without inhibitors is 4.34x10-6 mpy and the corrosion rate of brass with inhibitors is 2.51x10-6 mpy. In HCl media, the largest inhibitor efficiency was 7.52% by using guava leaf extract inhibitor with a ratio of volume water : ethanol 5:5 in HCl 0.05 M solution, where the corrosion rate of brass without inhibitors is 4.81x10-6 mpy and the corrosion rate of brass with inhibitors is 4,45x10-6 mpy.
Downloads
References
H., X. Salahudin, N. Mulyaningsih, “Analisa Penambahan Inhibitor Ekstrak Daun Teh Pada Pengait Crane Terhadap Laju Korosi,” Jurnal MER-C No. 2/Vol. 1, e-ISSN : 2622-5735, 2018
Asdim, “Penentuan Efisiensi Inhibisi Ekstrak Kulit Buah Manggis (Garcinia mangostana L.) pada Reaksi Korosi Baja dalam Larutan Asam,” Jurnal Gradien Vol.3 No.2, pp. 273-276, 2007.
Fachry, A Rasyid, RM. A. Sastrawan, and G. Svingkoe, “Kondisi Optimal Proses Ekstraksi Tanin dari Daun Jambu Biji Menggunakan Pelarut Etanol,” Prosiding STNK TOPI (7), 2012, pp. 69-73.
K.R. Thretewey, J. Chamberlain, ”Corrosion for Science and Engineering 2nd Ed,”London: Longman, 1995.
Haryono, Gogot, and B. Sugiarto, “Ekstrak Bahan Alam sebagai Inhibitor Korosi,” Yogyakarta: Jurusan Teknik Kimia FTI UPN Veteran, 2010.
S. Djaprie, “Ilmu dan Teknologi Bahan ed. 5,” Jakarta : Penerbit. Erlangga, 1995.
Kirk and Othmer, “Encyclopedia of Chemical Technology 2nd ed.”, New York : John Willey and Sons, 1965.
W. D., Callister Jr. and D.G. Rethwisch, “Materials Scienceand Engineering : An Introduction, 9th Edition,” Hoboken : John Wiley &Sons, Inc., 2013
Habibie, A. Lubis and A.E. Palupi, “Pengaruh Daun Teh dan Daun Jambu Biji sebagai Inhibitor Organik Alami pada Baja SS 304 dalam Larutan Asam,” Jurnal Teknik Mesin (JTM) 03 Nomor 01, 2014, pp. 9-13,
A. Jiménez-Escrig, M. Rincón, R. Pulido, and F. Saura-Calixto, “Guava Fruit (Psidium guajava L.) as a New Source of Antioxidant Dietary Fiber,” Journal of Agricultural and Food Chemistry 49 (11), 2001. pp. 5489-5493.
F. Ali, D. Saputri, and R. F. Nugroho, , “Pengaruh Waktu Perendaman dan Konsentrasi Ekstrak Daun Jambu Biji (Psidium Guajava, Linn) Sebagai Inhibitor Terhadap Laju Korosi Baja SS 304 Dalam Larutan Garam dan Asam,” Jurnal Teknik Kimia No.1, Vol 20, 2014, pp. 28-37.
G. Ubaydillah, N. Mulyaningsih, and C., “Pengaruh Penambahan Inhibitor Ekstrak Daun Jambu Biji Terhadap Laju Korosi Pada Rantai Dapra Kapal,” Jurnal MER-C No. 1/Vol.2, 2019.
T. Surdia, and K. Chijiiwa, “Teknologi Pengecoran Logam,” Jakarta Timur: Penerbit Balai Pustaka, 1987.
I. Cahyono, “Analisis Hasil Pengecoran Kuningan (CuZn) Dengan Variasi Media Pendinginan (Air Sumur, Oli SAE 40 dan Udara) Menggunakan Cetakan Pasir CO2,” Skripsi, Universitas Muhammadiyah Surakarta 2018
E.J. Rahayu, “Pengaruh Komposisi Kuningan (CuZn) Terhadap Kekuatan Impact, Kekerasan Dan Struktur Mikro Hasil Pengecoran Aluminium (Al) dengan Menggunakan Tungku Listrik,” Skripsi, Universitas Negeri Semarang, Semarang, 2018.
M.G. Fontana, “Corrosion Engineering. Third edition,” Singapore : McGraw-Hill Company, 1987.